You can uninstall or removes an installed libdvbpsi7 package itself from Debian 7 (Wheezy) through the terminal,
$ sudo apt-get remove libdvbpsi7
If you would like to remove libdvbpsi7 and it's dependent packages which are no longer needed from Ubuntu,
$ sudo apt-get remove --auto-remove libdvbpsi7
If you use with purge options to libdvbpsi7 package all the configuration and dependent packages will be removed.
$ sudo apt-get purge libdvbpsi7
If you use purge options along with auto remove, will be removed everything regarding the package, It's really useful when you want to reinstall again.
$ sudo apt-get purge --auto-remove libdvbpsi7